Tessensohn, Malcolm E.’s team published research in ChemPhysChem in 16 | CAS: 2240-88-2

ChemPhysChem published new progress about 2240-88-2. 2240-88-2 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol, name is 3,3,3-Trifluoropropan-1-ol, and the molecular formula is C6H12Br2, Safety of 3,3,3-Trifluoropropan-1-ol.

Tessensohn, Malcolm E. published the artcileMeasuring the Relative Hydrogen-Bonding Strengths of Alcohols in Aprotic Organic Solvents, Safety of 3,3,3-Trifluoropropan-1-ol, the publication is ChemPhysChem (2015), 16(1), 160-168, database is CAplus and MEDLINE.

Voltammetric experiments with 9,10-anthraquinone and 1,4-benzoquinone performed under controlled moisture conditions indicate that the hydrogen-bond strengths of alcs. in aprotic organic solvents can be differentiated by the electrochem. parameter ΔEpred = |Epred(1)-Epred(2)|, which is the potential separation between the two 1-electron reduction processes. This electrochem. parameter is inversely related to the strength of the interactions and can be used to differentiate between primary, secondary, tertiary alcs., and even diols, as it is sensitive to both their steric and electronic properties. The results are highly reproducible across two solvents with substantially different hydrogen-bonding properties (CH3CN and CH2Cl2) and are supported by d. functional theory calculations The numerous solvent-alc. interactions are less significant than the quinone-alc. hydrogen-bonding interactions. The utility of ΔEpred was illustrated by comparisons between (1) 3,3,3-trifluoro-n-propanol and 1,3-difluoroisopropanol and (2) ethylene glycol and 2,2,2-trifluoroethanol.

ChemPhysChem published new progress about 2240-88-2. 2240-88-2 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol, name is 3,3,3-Trifluoropropan-1-ol, and the molecular formula is C6H12Br2, Safety of 3,3,3-Trifluoropropan-1-ol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts