Li, Cheng published the artcileHighly efficient CO2 fixation into cyclic carbonate by hydroxyl-functionalized protic ionic liquids at atmospheric pressure, Recommanded Product: 2-Morpholinoethanol, the publication is Molecular Catalysis (2021), 111756, database is CAplus.
We report an efficient strategy for CO2 fixation into cyclic carbonates catalyzed by hydroxyl-functionalized protic ionic liquids (PILs) without any solvent and additive. Excellent yields of cyclic carbonates are obtained for the varied substrates under mild conditions (1 bar and 60°C). Mechanism studies have shown that hydroxyl promoted the activation of epoxide mols. through hydrogen bonding interaction, so that CO2 can be easily converted into the desired product of cyclic carbonates. In addition, the hydroxyl-functionalized PILs can also be recycled repeatedly. This hydroxyl-functionalized PILs-catalyzed process is proved to be a promising scheme for the chem. conversion of CO2.
Molecular Catalysis published new progress about 622-40-2. 622-40-2 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Alcohol, name is 2-Morpholinoethanol, and the molecular formula is C6H13NO2, Recommanded Product: 2-Morpholinoethanol.
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