Kownacki, Ireneusz’s team published research in Applied Catalysis, A: General in 380 | CAS: 17877-23-5

Applied Catalysis, A: General published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Category: alcohols-buliding-blocks.

Kownacki, Ireneusz published the artcileTris(triorganosilyl)phosphites-New ligands controlling catalytic activity of Pt(0) complex in curing of silicone rubber, Category: alcohols-buliding-blocks, the publication is Applied Catalysis, A: General (2010), 380(1-2), 105-112, database is CAplus.

Applying novel and efficient method, new tris(triorganosilyl)phosphites were synthesized and further used for the preparation of new well-defined platinum complexes [Pt(DVTMDS){P(OSiR3)3}] (DVTMDS = (H2C=CHSiMe2)2O, R3 = Si7O9(iOct)7, iPr3, MePh2, Ph3, (OtBu)3, (OSiMe3)3) which were well characterized by spectroscopic methods. Structures of two platinum(0) complexes, [Pt{η4-(H2C=CHSiMe2)2O}{P(OSiPh3)3}] (10) and [Pt{η4-(H2C=CHSiMe2)2O}{P(OSi(OtBu3))3}] (11) were determined by x-ray anal. The new complexes proved to be effective catalysts of a crosslinking of silicones via hydrosilylation at elevated temperature with relatively short cure time and the enthalpy of network formation similar to that of Pt-Karstedt’s/DAM (DAM = diallyl maleate) catalytic system. Addnl., the catalyzed silicone formulation had sufficiently long pot-life at room temperature

Applied Catalysis, A: General published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Category: alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts