Hoque, Anamul Md. published the artcileModes of interaction and thermodynamic behavior of aggregation of CTAB + BSA mixtures in diols media: effects of diols composition and temperature, Category: alcohols-buliding-blocks, the publication is Chemical Engineering Communications, database is CAplus.
The micellization of cetyltrimethylammonium bromide (CTAB) and bovine serum albumin (BSA) mixture has been studied conductometrically in aqueous solutions of different diols (1,2-propanediol (1,2-PrD), 2,3-butanediol (2,3-BD), and 1,5-pentanediol (1,5-PD)) media over the temperature range from 298.15 K to 323.15 K to gain insight into the mode and degree of interaction amongst the investigated constituents. The critical micelle concentration (cmc) values of the CTAB + BSA mixtures were attained initially low but enhanced with the rise in temperature in all the media studied. The values of the CTAB + BSA mixtures in the different diols media followed the order: The degree of micelle ionization (α) increased with increasing carbon chain length of diols and temperature The Gibbs free energy values associated with the micellization of the CTAB + BSA mixture were neg. and revealed a lowering of the spontaneity of micellization with increasing carbon chain length of the diols. The enthalpy and entropy changes of micellization revealed that the micellization was exothermic and mainly an enthalpy-controlled process in aqueous 1,2-PrD and 2,3-BD media while the process being endothermic, and entropy controlled in the 1,5-PD medium. The contribution of the solvent to the thermodn. parameters was assessed from free energy of transfer, enthalpy of transfer, and entropy of transfer values. The enthalpy-entropy compensation parameters were also studied and discussed with proper reasoning.
Chemical Engineering Communications published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C5H12O2, Category: alcohols-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts