Chung, Sheng-Hsuan published the artcileSynthesis of boron-containing primary amines, Recommanded Product: [4-Fluoro-3-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanol, the publication is Molecules (2013), 18(10), 12346-12367, database is CAplus and MEDLINE.
B-containing primary amines were synthesized for use as building blocks in the study of peptoids. In the 1st step, Gabriel synthesis conditions were modified to enable the construction of seven different aminomethylphenyl boronate esters, e.g., p-(pinB)C6H4CH2NH2 (Bpin = 4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl), in good to excellent yields. These compounds were further used to build peptoid analogs via an Ugi four-component reaction (Ugi-4CR) under microwave irradiation The prepared Ugi-4CR boronate esters were then successfully converted to the corresponding boronic acids. Finally, the peptoid structures were successfully modified by cross-coupling to aryl/heteroaryl chlorides via a Pd-mediated Suzuki coupling reaction to yield the corresponding derivatives in moderate to good yields.
Molecules published new progress about 1333264-06-4. 1333264-06-4 belongs to alcohols-buliding-blocks, auxiliary class Boronic acid and ester,Boronic acid and ester, name is [4-Fluoro-3-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanol, and the molecular formula is C13H18BFO3, Recommanded Product: [4-Fluoro-3-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanol.
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