Blundell, Toby J. published the artcileEnantiopure and racemic radical-cation salts of B(mandelate)2– and B(2-chloromandelate)2– anions with BEDT-TTF, Related Products of alcohols-buliding-blocks, the publication is Dalton Transactions (2022), 51(12), 4843-4852, database is CAplus and MEDLINE.
Authors report the first examples of radical-cation salts of BEDT-TTF with spiroborate anions [B(mandelate)2]– and [B(2-chloromandelate)2]–, synthesized from either enantiopure or racemic bidentate mandelate or chloromandelate ligands. In the salts prepared using enantiopure ligands only one of two diastereoisomers of the spiroborate anion is incorporated, with the boron center having the same stereochem. as the enantiopure ligand. For the racemic salts one racemic pair of spiroborate anions containing an R and an S mandelate ligand is incorporated. In certain solvents helical crystals were obtained when using spiroborate anions with enantiopure ligands. Elec. and magnetic properties, and band structure calculations are reported.
Dalton Transactions published new progress about 90-64-2. 90-64-2 belongs to alcohols-buliding-blocks, auxiliary class Carboxylic acid,Benzene,Alcohol,Natural product, name is 2-Hydroxy-2-phenylacetic acid, and the molecular formula is C8H8O3, Related Products of alcohols-buliding-blocks.
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