Xu, Shibo published the artcileNickel-Catalyzed Regio- and Stereospecific C-H Coupling of Benzamides with Aziridines, Application of 2-Aminobutan-1-ol, the publication is Organic Letters (2021), 23(14), 5471-5475, database is CAplus and MEDLINE.
A nickel-catalyzed C-H coupling of 8-aminoquinoline-derived benzamides with aryl- and alkyl-substituted aziridines was disclosed. The current strategy provided direct access to benzolactams by the C-H alkylation-intramol. amidation cascade event with the concomitant removal of the aminoquinoline auxiliary. The regioselectivity of ring opening of aziridines was controlled by the substituents. The reaction with chiral aziridines proceeded with inversion of configuration, thus suggesting an SN2-type nucleophilic ring-opening pathway.
Organic Letters published new progress about 96-20-8. 96-20-8 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Alcohol, name is 2-Aminobutan-1-ol, and the molecular formula is C11H24O3, Application of 2-Aminobutan-1-ol.
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