Waterland, R. L. published the artcileGas phase UV and IR absorption spectra of CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (χ = 2, 3, 4), Safety of 3,3,3-Trifluoropropan-1-ol, the publication is Journal of Fluorine Chemistry (2005), 126(9-10), 1288-1296, database is CAplus.
The UV and IR spectra of CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (χ = 2, 3, 4) were studied using computational and exptl. techniques. Computational methods were used to show that CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (χ = 2, 3) have UV absorption at λ = 140-175 nm. Photolysis is therefore not a significant environmental loss mechanism for fluorinated alcs. Exptl. methods were used to record IR spectra for CF3CH2CH2OH and F(CF2CF2)xCH2CH2OH (χ = 2, 3, 4) at spectral resolutions of 0.004-0.5 cm-1 with, and without, 700 torr of air diluent. There was no discernable effect of total pressure or spectral resolution over the range studied. Calculated IR spectra agreed with those measured exptl., and were used to assign the IR spectra.
Journal of Fluorine Chemistry published new progress about 2240-88-2. 2240-88-2 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol, name is 3,3,3-Trifluoropropan-1-ol, and the molecular formula is C12H25Br, Safety of 3,3,3-Trifluoropropan-1-ol.
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