Soeta, Takahiro published the artcileN-Heterocyclic Carbene-Catalyzed Chemoselective Monoacylation of 1,n-Linear Diols, Application In Synthesis of 111-29-5, the publication is Organic Letters (2021), 23(21), 8138-8142, database is CAplus and MEDLINE.
This paper discusses the N-heterocyclic carbene (NHC)-catalyzed redox monoacylation of 1,n-linear diols using α-benzoyloxyaldehydes. The reactions afforded monoacylated diols in moderate to good selectivities and chem. yields. Authors original NHC bearing a pyridine moiety plays an important role in achieving good chemoselectivities. A wide range of 1,n-linear diols were successfully applied to this reaction.
Organic Letters published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C12H16O3, Application In Synthesis of 111-29-5.
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