Seitz, Ann-Katrin published the artcileConcentrated Aqueous Peroxodicarbonate: Efficient Electrosynthesis and Use as Oxidizer in Epoxidations, S-, and N-Oxidations, Related Products of alcohols-buliding-blocks, the publication is Angewandte Chemie, International Edition (2022), 61(25), e202117563, database is CAplus and MEDLINE.
Peroxodicarbonates are of substantial interest as potentially powerful and sustainable oxidizers but have so far been accessible only in low concentrations with unsatisfactory energy efficiency. Concentrated (> 0.9 mol L-1) peroxodicarbonate solutions have now been made accessible by the electrolysis of aqueous K2CO3/Na2CO3/KHCO3 solutions at high c.d. of 3.33 A cm-2 in an efficiently cooled circular flow reactor equipped with a boron-doped diamond anode and a stainless-steel cathode. Their synthetic potential as platform oxidizers was clearly demonstrated in transformations including sulfoxidation, N-oxidation, and epoxidation
Angewandte Chemie, International Edition published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C8H11NO, Related Products of alcohols-buliding-blocks.
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