MacQueen, Blake published the artcileOptimum Reaction Conditions for 1,4-Anhydroerythritol and Xylitol Hydrodeoxygenation over a ReOx-Pd/CeO2 Catalyst via Design of Experiments, Related Products of alcohols-buliding-blocks, the main research area is anhydroerythritol xylitol hydrodeoxygenation ReO palladium Ceria catalyst.
In this study, we demonstrate that for the simultaneous hydrodeoxygenation (HDO) of 1,4-anhydroerythritol a comparable yield of THF is obtained at half the previously reported H2 pressure. The simultaneous hydrodeoxygenation was conducted using a heterogeneous ReOx-Pd/CeO2 catalyst. An L9 Taguchi design of experiment was enacted to elucidate the temperature, pressure, and catalyst loading effects on the yield of the HDO reaction by testing pressures ranging from 40 to 80 bar H2, temperatures of 100-180 °C, and Re loadings of 2-4 weight %. Our design showed that the yield of this reaction is significantly affected by the reaction temperature only. An L9 Taguchi design was conducted for xylitol simultaneous hydrodeoxygenation with pressures ranging from 5 to 10 bar H2, temperatures of 140-180 °C, and Re loadings of 2-4 weight %. The xylitol design elucidated the direct relation of pressure, and the inverse relation of temperature and catalyst loading, to yield with the optimal reaction condition being 140 °C and 10 bar H2.
Industrial & Engineering Chemistry Research published new progress about Deoxidation. 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Related Products of alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts