Kitazume, Tomoya published the artcileUltrasound-promoted selective perfluoroalkylation on the desired position of organic molecules, HPLC of Formula: 83706-94-9, the publication is Journal of the American Chemical Society (1985), 107(18), 5186-91, database is CAplus.
Perfluoroalkylzinc iodides or bromides were prepared from perfluoroalkyl iodides or bromides and Zn powder in DMF or THF with ultrasonic irradiation, and were used as regioselective perfluoroalkylating reagents for the preparation of a wide variety of perfluoroalkylated compounds Ultrasound-promoted asym. induction with a perfluoroalkyl group on the asym. carbon was achieved by reaction of perfluoroalkyl halides with optically active enamines in the presence of zinc powder and dichlorobis(π-cyclopentadienyl)titanium.
Journal of the American Chemical Society published new progress about 83706-94-9. 83706-94-9 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethylated Building Blocks, name is (E)-4,4,4-Trifluorobut-2-en-1-ol, and the molecular formula is C4H5F3O, HPLC of Formula: 83706-94-9.
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