Javed, Mahjabeen published the artcileProgrammable Shape Change in Semicrystalline Liquid Crystal Elastomers, Computed Properties of 7575-23-7, the main research area is programmable shape change semicrystalline liquid crystal elastomer; actuator; crystallization; liquid crystal elastomers; polymers; stimuli-responsive.
Liquid crystal elastomers (LCEs) are stimuli-responsive materials capable of reversible and programmable shape change in response to an environmental stimulus. Despite the highly responsive nature of these materials, the modest elastic modulus and blocking stress exhibited by these actuating materials can be limiting in some engineering applications. Here, we engineer a semicrystalline LCE, where the incorporation of semicrystallinity in a lightly cross-linked liquid crystalline network yields tough and highly responsive materials. Directed self-assembly can be employed to program director profiles through the thickness of the semicrystalline LCE. In short, we use the alignment of a liquid crystal monomer phase to pattern the anisotropy of a semicrystalline polymer network. Both the semicrystalline-liquid crystalline and liquid crystalline-isotropic phase transition temperatures provide controllable shape transformations. A planarly aligned sample’s normalized dimension parallel to the nematic director decreases from 1 at room temperature to 0.42 at 250°. The introduction of the semicrystalline nature also enhances the mech. properties exhibited by the semicrystalline LCE. Semicrystalline LCEs have a storage modulus of 390 MPa at room temperature, and monodomain samples are capable of generating a contractile stress of 2.7 MPa on heating from 25 to 50°, far below the nematic to isotropic transition temperature The robust mech. properties of this material combined with the high actuation strain can be leveraged for applications such as soft robotics and actuators capable of doing significant work.
ACS Applied Materials & Interfaces published new progress about Actuators. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, Computed Properties of 7575-23-7.
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