Hirano, Tomohiro published the artcileSyndiotactic-specific radical polymerization of N-isopropylacrylamide in toluene at low temperatures in the presence of silyl alcohols, Application In Synthesis of 17877-23-5, the publication is Polymer International (2012), 61(6), 966-970, database is CAplus.
The radical polymerization of N-isopropylacrylamide was carried out in toluene at low temperatures in the presence of silyl alcs., such as triethylsilanol. Poly(N-isopropylacrylamide) with a racemo dyad content of 75% was obtained at – 80° with a 4:1 triethylsilanol to monomer ratio loading. NMR anal. suggests that the mechanism for syndiotactic induction, in the presence of silyl alcs., may be similar to that observed with alkyl alcs. In this case, a 1:2 complex formation, via hydrogen bonding interactions, leads to the induction of syndiotactic specificity. Copyright © 2012 Society of Chem. Industry.
Polymer International published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Application In Synthesis of 17877-23-5.
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