Guzman, Dailyn’s team published research in Reactive & Functional Polymers in 2019-03-31 | CAS: 7575-23-7

Reactive & Functional Polymers published new progress about Allylation. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, SDS of cas: 7575-23-7.

Guzman, Dailyn published the artcileFully renewable thermosets based on bis-eugenol prepared by thiol-click chemistry, SDS of cas: 7575-23-7, the main research area is fully renewable thermoset bis eugenol thiol click chem.

Thiol-ene photocuring and thiol-epoxy thermal curing have been applied to prepare new thermosets from renewable substrates. As monomers, a tetrallyl and a tetraepoxy derivative of bis-eugenol were prepared by dimerization of eugenol, allylation and further epoxidation These compounds were reacted with a com. available tetrathiol, PETMP, and thiols synthesized from two natural resources as squalene (6SH-SQ) and eugenol (3SH-EU) in photoinitiated and thermal conditions. The reaction process was studied by calorimetry, and the materials obtained were characterized by thermogravimetry, thermomech. studies and mech. testing. Thiol-epoxy materials showed a better mech. performance than thiol-ene photocured thermosets. This new epoxy monomer of renewable origin allowed to prepare materials with final properties better than those obtained from the diglycidylether of bisphenol A, owing to the high functionality of bis-eugenol and its rigid and compact structure.

Reactive & Functional Polymers published new progress about Allylation. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, SDS of cas: 7575-23-7.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts