Blute, Irena published the artcilePhase behavior of alkyl glycerol ether surfactants, Category: alcohols-buliding-blocks, the publication is Tenside, Surfactants, Detergents (1998), 35(3), 207-212, database is CAplus.
The phase behavior and phys. properties of a series of alkyl (C6, C8, C12 and iso-C8) monoglycerol ethers and 2-hydroxyalkyl (C6, C8, C12) monoglycerol ethers are presented. The binary phase diagram for the surfactants shows very little dependence on temperature It can be seen that as the alkyl chain length increases the tendency to form lamellar liquid crystalline phases increases. The branched alkyl chain shows no formation of lamellar phases even at high concentrations of surfactant. The difference in phase behavior between the surfactants is attributed to the variation in the critical packing parameter of the surfactants. The presence of an addnl. hydroxyl group in the alkyl chain causes temperature-independent solubility behavior. Ternary phase diagrams were prepared using dodecane as the oil phase. Hexyl glycerol ether was the only one of the alkyl glycerol ethers that was sufficiently water-soluble to determine the surface tension and CMC. The CMC was 15 mM and surface tension was 26 mN m-1.
Tenside, Surfactants, Detergents published new progress about 70445-33-9. 70445-33-9 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is 3-((2-Ethylhexyl)oxy)propane-1,2-diol, and the molecular formula is C11H24O3, Category: alcohols-buliding-blocks.
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