Asahara, Teruzo published the artcileTelomerization of ethylene and carbon tetrachloride initiated by amines, Quality Control of 4543-95-7, the publication is Bulletin of the Japan Petroleum Institute (1965), 35-40, database is CAplus.
cf. CA 62, 1554a. In this reaction, strongly basic amines are excellent initiators. Primary amines are more effective than secondary or tertiary structures, and branched amines are inferior to n-amines. Alkanolamines are also excellent initiators. The experiments were carried out in a stainless steel autoclave in the absence of metallic salts. tert-Butanol is a preferred solvent for this reaction. Generally, the higher the dielec. constant of the hydroxylic solvent, the greater the yield of telomer. Aprotic solvents show no such regular influence. 13 references.
Bulletin of the Japan Petroleum Institute published new progress about 4543-95-7. 4543-95-7 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Alcohol, name is 4-(Butylamino)butan-1-ol, and the molecular formula is C8H19NO, Quality Control of 4543-95-7.
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