Zhang, Tongfei published the artcileCopper-catalyzed thioketalization of enones featuring trifluoromethyl groups, Computed Properties of 4410-99-5, the publication is RSC Advances (2021), 11(32), 19832-19835, database is CAplus and MEDLINE.
Here, a copper-catalyzed thioketalization of enones bearing CF3 groups and various mercaptans was developed, thioketal mols. I [R = Et, i-Pr, allyl, etc.; RR = (CH2)2; R2 = Me, Ph] had been obtained with moderate to excellent yield. Meanwhile, a preparative scale experiment had been performed giving over 95% yield. This work allowed the straightforward formation of thioketals I containing CF3 groups and unsaturated double bonds.
RSC Advances published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C7H15NO, Computed Properties of 4410-99-5.
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