Weber, Edwin published the artcileVersatile and convenient lattice hosts derived from singly bridged triarylmethane frameworks. X-ray crystal structures of three inclusion compounds, Computed Properties of 596-38-3, the publication is Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) (1990), 2167-77, database is CAplus.
A new family of host mols., based on the singly bridged triarylmethanol and triarylacetic acid frameworks, is described. These hosts form crystalline inclusions with a variety of uncharged organic mols. ranging from protic dipolar to apolar compounds (130 different species). The formation and stoichiometry depend in a systematic manner on structural parameters of the host, such as the nature of the functional group and the substituents, and on the substituent positions. The crystal structures of three inclusion compounds [I (R = OH)·benzene (8:3), I (R = OH)·dioxane (4:3), and I (R = CO2H)·EtOH (1:1)] have been studied by x-ray diffraction. They reveal the building principles of the new inclusion family. In the crystals of I (R = OH)·benzene (8:3), the benzene is interstitially entrapped by H-bonded tetramer clusters of I (R = OH). Crystals of I (R = OH)·dioxane (4:3) are built of H-bonded 2:1 host-guest complexes including interstitial mols. of dioxane. In the case of I (R = CO2H)·EtOH (1:1), the building principle is formation of 2:2 host-guest clusters via a twelve-membered H-bonded ring.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) published new progress about 596-38-3. 596-38-3 belongs to alcohols-buliding-blocks, auxiliary class Other Aromatic Heterocyclic,Benzene,Alcohol, name is 9-Phenyl-9H-xanthen-9-ol, and the molecular formula is C17H18N2O6, Computed Properties of 596-38-3.
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