Wang, Peng published the artcileSolvent-free, B(C6F5)3-Catalyzed S-H Insertion of Thiophenols and Thiols with α-Diazoesters, Quality Control of 4410-99-5, the publication is Chemistry – An Asian Journal (2022), 17(16), e202200465, database is CAplus and MEDLINE.
A B(C6F5)3-catalyzed S-H insertion reaction of thiophenols and thiols with α-diazoesters to access valuable α-thioesters was described. With the established protocol, an array of α-thioester products were generated in moderate to good yields with broad scope and functional group tolerance. In addition, this reaction maintained its high efficiency on gram scale and the product can be easily transformed into other useful motifs. This reaction proceeded under solvent-free conditions at room temperature, and generally finished in twenty minutes upon magnet stirring, which offers an expedient way for synthesis of thioether-containing compounds
Chemistry – An Asian Journal published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C8H11NO, Quality Control of 4410-99-5.
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