Villemin, Elise published the artcilePolydiacetylene Nanotubes in Heterogeneous Catalysis: Application to the Gold-Mediated Oxidation of Silanes, Synthetic Route of 17877-23-5, the publication is Macromolecular Chemistry and Physics (2015), 216(24), 2398-2403, database is CAplus.
A layer-by-layer approach is used to anchor small gold nanoparticles onto organic nanotubes resulting from the self-assembly and polymerization of diacetylene-containing nitrilotriacetic amphiphiles. The obtained nanotube-gold hybrid is used as a catalyst for the aerobic oxidation of various silanes. With minimal gold loading (0.05 mol%), all substrates are converted into the corresponding silanols with hydrogen gas as the only byproduct. The catalyst operates under mild conditions and can be easily recycled, losing neither activity nor selectivity.
Macromolecular Chemistry and Physics published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C6H8O3, Synthetic Route of 17877-23-5.
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