Singh, Gurjaspreet published the artcileSelective mercury ion recognition using a methyl red (MR) based silatrane sensor, Safety of Triisopropanolamine, the publication is New Journal of Chemistry (2018), 42(8), 6315-6321, database is CAplus.
A new Methyl red (MR) based silatrane was synthesized in high yield by the transesterification reaction of Methyl red-amidopropyltrimethoxysilane 1 (MR-APTMS) and trisisopropanolamine. Single crystal x-ray diffraction anal. was used to deduce the structure of silatrane 2 which was also supported by NMR (1H, 13C) spectroscopy, mass spectrometry, FTIR, UV-visible and DFT studies. Silatrane 2 when surveyed for cation recognition ability with a library of metal ions in CH3CN/H2O (9 : 1, volume/volume) was found to act as an excellent UV-visible probe for the selective recognition of Hg2+in vitro. Also, quantum mech. calculations of the interaction complex [MR-APS-Hg]2+3 using DFT at the B3LYP level in conjunction with the LanL2DZ basis set determined the geometric and the stability parameters of the surveyed interaction.
New Journal of Chemistry published new progress about 122-20-3. 122-20-3 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment, name is Triisopropanolamine, and the molecular formula is C8H6ClN, Safety of Triisopropanolamine.
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