Sharma, Hemant K. published the artcileSiloxymethylamines as aminomethylation reagents for amines leading to labile diaminomethanes that can be trapped as their [Mo(CO)4] complexes, Computed Properties of 597-52-4, the publication is Chemistry – A European Journal (2016), 22(22), 7363-7366, database is CAplus and MEDLINE.
Compound Et3SiOCH2NMe2 transfers the aminomethyl group, Me2NCH2 to R2NH (R2 = Et2, PhMe, [Cr(η6-C6H5)(CO)3]Me, PhH) giving previously unknown diaminomethanes, Me2NCH2NR2 and, in the case of R2 = PhH, the triamine Me2NCH2N(Ph)CH2NMe2. The diaminomethanes exhibit an unreported disproportionation to a mixture of (R2N)2CH2, (Me2N)2CH2, and Me2NCH2NR2, which can be trapped as their [Mo(CO)4(diamine)] complexes. Whereas PhMeNCH2NMe2 is a labile compound, the metal-substituted [(η6-C6H5)Cr(CO)3]MeNCH2NMe2 is a stable material. The triamine Me2NCH2N(Ph)CH2NMe2 is unstable with respect to transformation to 1,3,5-triphenyltriazine, but is readily trapped as the bidentate-triamine Mo(CO)4 complex. All metal complexes were characterized by single-crystal x-ray diffraction.
Chemistry – A European Journal published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C4H6O3, Computed Properties of 597-52-4.
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