John, Jubi published the artcileCatalytic Oxidation of Silanes by Carbon Nanotube-Gold Nanohybrids, Computed Properties of 17877-23-5, the publication is Angewandte Chemie, International Edition (2011), 50(33), 7533-7536, S7533/1-S7533/37, database is CAplus and MEDLINE.
Here reported an alternative strategy which has led to the discovery of the most efficient catalytic system to date for silane oxidation The approach involves layer-by-layer (LBL) assembly of gold nanoparticles on carbon nanotubes (CNT5). Nanotubes provide high sp. surface area and excellent nanoparticle (NP) dispersion. In addition, nanotubes are electronically active and stabilization of transient higher oxidation states of gold are anticipated by collaborative interactions with the metal. To the best of authors knowledge, this is the first report on silane oxidation by CNT-supported catalysts. Thus, gold carbon nanotube catalyzed oxidation of PhSiMe2H in THF/H2O in the presence of air gave 98% PhSiMe2OH in 45m at room temperature
Angewandte Chemie, International Edition published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Computed Properties of 17877-23-5.
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