Dindarloo Inaloo, Iman published the artcileNickel-Catalyzed Synthesis of N-(Hetero)aryl Carbamates from Cyanate Salts and Phenols Activated with Cyanuric Chloride, Application of Thiophen-3-ol, the publication is ChemCatChem (2020), 12(21), 5486-5491, database is CAplus.
A simple and efficient domino reaction has been designed and employed for the one-pot synthesis of N-(hetero)aryl carbamates ArNHC(O)OR (Ar = Ph, thiophen-2-yl, pyridin-3-yl, etc.; R = Pr, cyclohexyl, allyl, etc.) through the reaction between alcs. ROH and in-situ produced (hetero)aryl isocyanates in the presence of a nickel catalyst. The phenolic C-O bond was activated via the reaction of phenol with cyanuric chloride (2,4,6-trichloro-1,3,5-triazine (TCT)) as an inexpensive and readily available reagent. This strategy provides practical access to N-(hetero)aryl carbamates in good yields with high functional groups compatibility.
ChemCatChem published new progress about 17236-59-8. 17236-59-8 belongs to alcohols-buliding-blocks, auxiliary class Thiophene,Alcohol, name is Thiophen-3-ol, and the molecular formula is C4H4OS, Application of Thiophen-3-ol.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts