Chen, Xincheng published the artcileTheoretical study on the reaction of Et3GeCH:CH2 with Et3SiOH, Recommanded Product: Triethylsilanol, the publication is Advanced Materials Research (Durnten-Zurich, Switzerland) (2012), 301-304, database is CAplus.
The reaction of Et3GeCH:CH2 + Et3SiOH → Et3SiO-Ge-Et3 + CH2:CH2 has been studied using quantum chem. methods. Geometries of reactants, transition states, and products have been optimized resp. at the B3LYP/6-311+g(2d,2p) level. The rate constants were evaluated using canonical variational transition state theory (CVT) and canonical variational transition state theory with small-curvature tunneling contributions (CVT/SCT) over the temperature range of 200-3500K. The CVT/SCT rate constants exhibit typical non-Arrhenius behavior, and a three-parameter rate-temperature formula has been fitted as follows: k(T)=1.43 × 10-38T5.41exp(-13200/T) (in units of cm3 mol.-1s-1).
Advanced Materials Research (Durnten-Zurich, Switzerland) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Recommanded Product: Triethylsilanol.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts