Arzumanyan, Ashot V.’s team published research in Synlett in 29 | CAS: 597-52-4

Synlett published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Formula: C6H16OSi.

Arzumanyan, Ashot V. published the artcileCopper-Catalyzed Oxidation of Hydrosilanes: A New Method for the Synthesis of Alkyl- and Siloxysilanols, Formula: C6H16OSi, the publication is Synlett (2018), 29(4), 489-492, database is CAplus.

A simple method for the preparation of silanols from the corresponding hydrosilanes is reported. The method employs a com. available oxidizing system based on CuCO 3/ t-BuOOH (aq)under relatively mild conditions (80 °C, atm. pressure) with acetonitrile as the solvent. Furthermore, we present a method that permits the Si-H group to be oxidized to a Si-OH group not only in triethylsilane, but also in bis(trimethylsiloxy)methylsilane, a siloxy derivative of hydrosilane. The products were isolated in gram amounts in yields of 61-73%.

Synlett published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Formula: C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts