Yoshimura, Yukihiro published the artcileRaman investigation on the local structure of alcohols in 1-butyl-3-methylimidazolium tetrafluoroborate, Application In Synthesis of 111-87-5, the main research area is alc ionic liquid hydrogen bond cluster Raman spectra conformation.
In this study, we investigated the evolution of the local structure of a series of primary alcs. from methanol to octanol in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) as a function of alc. concentration using Raman spectroscopy, with the aim of gaining more insight into the fundamentals of the compelling ionic liquid-mol. solvent interactions at mol. level. The Raman spectra revealed the presence of various types of O-H species in the mixtures, with the major fractions at low alc. concentration corresponding to monomers, which indicates that most of the alc. mols. are isolated from each other. A plausible picture for the changes in the local structures of alc. mols. loosely confined in the [bmim][BF4] matrix is presented, which suggests the occurrence of conformational changes in the bmim+ cation and the alc. mols. This observation may indicate a unique evolution of the local structure of alc. clusters formed in the ionic liquid
Journal of Molecular Liquids published new progress about Clusters. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Application In Synthesis of 111-87-5.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts