James, Kenneth published the artcileThe synthesis of per-O-benzyl-α-D-galactosyl and -α-L-fucosyl bromides, Related Products of alcohols-buliding-blocks, the main research area is hexopyranosyl perbenzylated bromide; galactopyranosyl perbenzylated bromide; fucopyranosyl perbenzylated bromide; benzylated hexopyranosyl bromide.
The title galactosyl bromide was prepared by benzylation of allyl galactopyranoside, with PhCH2Br-NaH, isomerization of the allyl group with tert-BuOK-Me2SO to prop-1-enyl tetra-O-benzyl-β-D-galactopyranoside. Removal of the vinyl residue with HgO and reaction with p-O2NC6H4COCl gave the tetra-O-benzyl-1-O-p-nitrobenzoyl-D-galactopyranose (I). Treatment of I with HBr gave 80% of the α-bromide as an oil. The fucopyranosyl derivative was prepared similarly.
Australian Journal of Chemistry published new progress about hexopyranosyl perbenzylated bromide; galactopyranosyl perbenzylated bromide; fucopyranosyl perbenzylated bromide; benzylated hexopyranosyl bromide. 2595-07-5 belongs to class alcohols-buliding-blocks, name is (2R,3R,4S,5R,6R)-2-(Allyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol, and the molecular formula is C9H16O6, Related Products of alcohols-buliding-blocks.
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