Allegrezza, Michael L. published the artcilePhotocatalyzed thiol-alkene coupling: Mechanistic study and polymer synthesis, Related Products of alcohols-buliding-blocks, the main research area is photocatalyst thiol alkene coupling polymer crosslinked.
Due to the “”click”” chem. characteristics of the thiol-ene reaction, these transformations have been gaining an increasing amount of attention in current chem. research. The high efficiency and selectivity of these transformations have been useful for many areas of study, from small mol. organic synthesis, to polymer synthesis and functionalization, to bio-conjugation reactions. In this work, a study of a novel method of photochem. thiol-ene reactions using alkyl halides and an tris[2-phenylpyridinato-C2,N]iridium(III) (Ir(ppy)3) photocatalyst is investigated. This process is shown to progress rapidly and has the benefit of low catalyst and initiator concentrations relative to reagents as well as mild conditions associated with photochem. processes. To understand the mechanism of this process, catalyst and initiator concentrations and other reaction conditions are varied. To demonstrate the utility of this process, a step-growth thiol-ene polymer is synthesized using dithiol and diene monomers and a crosslinked polymer network is synthesized as well. © 2019 Wiley Periodicals, Inc.J. Polym. Sci., Part A: Polym.Chem. 2019.
Journal of Polymer Science, Part A: Polymer Chemistry published new progress about Loss modulus. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, Related Products of alcohols-buliding-blocks.
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Alcohol – Wikipedia,
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