Allcock, Harry R. published the artcilePolyphosphazenes bearing polymerizable pyrrole, thiophene, and furan side groups: synthesis and chemical oxidation, HPLC of Formula: 50966-69-3, the main research area is polyphosphazene preparation polymerizable heterocycle containing; furan containing polyphosphazene preparation doping; pyrrole containing polyphosphazene preparation doping; thiophene containing polyphosphazene preparation doping; doping polyphosphazene polymerizable heterocycle containing; conductivity heterocycle containing polyphosphazene.
Several polyorganophosphazenes containing polymerizable, heterocyclic side groups, (e.g., furan, thiophene, and pyrrole derivatives) were prepared by reaction of polydichlorophosphazenes with the Na salt of the corresponding hetercyclic alkoxide. The prepared polyphosphazines were doped with Fe(ClO4)3, FeCl3, or I to give semi-conductive polymers, and the conductivity is discussed with respect to polymerization of the heterocycle within the polymer. The prepared polymers were characterized by NMR spectroscopy, gel permeation chromatog., elemental microanal., and DSC. Possible explanations for the relatively low conductivity of the polymers are discussed, including interchain hopping distances, insolubility of the crosslinked polymers, and immobilization of the heterocyclic side groups. The last 2 factors may serve to minimize heterocyclic polymer chain growth, thereby keeping the resultant conductivity low.
Chemistry of Materials published new progress about Crosslinking. 50966-69-3 belongs to class alcohols-buliding-blocks, name is 3-(1H-Pyrrol-1-yl)propan-1-ol, and the molecular formula is C7H11NO, HPLC of Formula: 50966-69-3.
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