Ramirez-Contreras, Rodrigo published the artcileChemo- and Regioselective Functionalization of Polyols through Catalytic C(sp3)-C(sp3) Kumada-Type Coupling of Cyclic Sulfate Esters, Synthetic Route of 58783-82-7, the main research area is chemoselective regioselective functionalization Kumada type coupling cyclic sulfate ester; copper catalyst coupling cyclic sulfate ester alkyl Grignard reagent.
This contribution describes a copper-catalyzed, C(sp3)-C(sp3) cross-coupling reaction of cyclic sulfate esters, a distinct class of electrophilic derivatives of polyols, with alkyl Grignard reagents to afford functionalized alc. products in good yields. The method is operationally simple and highlights the potential of cyclic sulfate esters as highly reactive substrates in catalytic, chemoselective polyol transformations.
Organic Letters published new progress about Coupling reaction. 58783-82-7 belongs to class alcohols-buliding-blocks, name is 5-Tridecanol, and the molecular formula is C13H28O, Synthetic Route of 58783-82-7.
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