Ramesh, Madhan published the artcileHalf-Sandwich η6-p-Cymene) Ruthenium(II) complexes bearing 5-Amino-1-Methyl-3-Phenylpyrazole Schiff base ligands: Synthesis, structure and catalytic transfer hydrogenation of ketones, Related Products of alcohols-buliding-blocks, the main research area is ruthenium Schiff base complex preparation; alc preparation; ketone transfer hydrogenation ruthenium catalyst.
New (η6-p-cymene)ruthenium(II) complexes containing Schiff base ligands of the general composition [RuCl(η-p-cymene)(L)] were synthesized and screened for their efficiency as catalysts in the transfer hydrogenation of various ketones to alcs. RCH(OH)R1 [R = Et, Ph, 4-ClC6H4, etc.; R1 = Me, Et, Ph; RR1 = (CH2)4, (CH2)5] showing excellent conversion up to 99%. The complexes were characterized by anal. and spectral (FT-IR, UV-Vis, 1H NMR and 13C NMR) methods and the mol. structure of complex I was determined by single crystal X-ray diffraction studies, revealing a pseudo-octahedral piano stool geometry around ruthenium(II) ion. Under the optimized conditions, the influence of base, reaction temperature and substrate scope was also reported.
Journal of Organometallic Chemistry published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Related Products of alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts