Wu, Zhilei published the artcileCopper(I) iodide cluster-based lanthanide organic frameworks: synthesis and application as efficient catalysts for carboxylative cyclization of propargyl alcohols with CO2 under mild conditions, Synthetic Route of 107-54-0, the main research area is dysprosium copper nicotinate metal organic framework preparation crystal structure; gadolinium copper isonicotinate metal organic framework preparation crystal structure; carboxylative cyclization propargyl alc carbon dioxide lanthanide MOF catalyzed.
Two metal-organic frameworks (MOFs), namely, [Dy2Cu4I4(NA)6(DMF)2]n (1) and [Gd2Cu2I2(IN)6(DMF)4]·5DMF (2) (HNA = nicotinic acid, HIN = isonicotinic acid), constructed based on lanthanide ions and copper iodide clusters ([Cu4I4] and [Cu2I2]) were successfully synthesized and characterized. Compound 1 has a three-dimensional framework and compound 2 displays a two-dimensional plane with sql topol., resp. Both of them exhibit high thermostability and solvent stabilities. Addnl., catalytic explorations reveal that 1 displays higher catalytic activity than 2 for the carboxylic cyclization of propargyl alcs. More importantly, 1 also exhibits excellent catalytic performance in the carboxylation reactions of CO2 and terminal propargylic alcs. with various substituents. To the best of authors knowledge, this is the first example of non-noble metal based MOF catalysts for the carboxylative cyclization of propargyl alcs. with CO2 under atm. pressure and at room temperature, which provides a highly promising approach for MOFs in the catalytic conversion of CO2 to valuable chems.
Dalton Transactions published new progress about Alcohols, propargyl Role: RCT (Reactant), RACT (Reactant or Reagent). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Synthetic Route of 107-54-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts