Wu, Yao published the artcileA Copper Iodide Cluster-Based Metal-Organic Polyhedra for Photocatalytic Click Chemistry, Product Details of C8H14O, the main research area is phenyl triazole preparation click chem; aryl acetylene benzyl azide alkyne cycloaddition copper iodide photocatalyst.
Herein, a copper(I) iodide cluster-based metal-organic polyhedra (Cu3I3)4L14 (1) ((L1 = 1,3,5-trispyridylsulfanylethyl)-2,4,6-triethylbenzene, 2-mercaptopyridine) is synthesized. Due to the abnormal geometry of [Cu3I3] SBUs, MOP 1 exhibits a half-truncated cube topol., which is rarely observed up to date. Compared with commonly used metal ion or clusters, the coordination bond between the [Cu3I3] SBU and the ligand is rather labile in solution evidenced by the theor. calculations and exptl. results. Interestingly, the liable [Cu3I3] SBU endows MOP 1 to photocatalyze the azide-alkyne cycloaddition reaction in aqueous solution with high efficiency, excellent tolerance (>80% isolated yield for 18 examples), and good recyclability. The mechanistic studies reveal a photoinduced electron transfer from the MOP to azide, which is unusual in copper-catalyzed click reactions.
Small Structures published new progress about 1,3-Dipolar cycloaddition catalysts (azide-alkyne, regioselective). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Product Details of C8H14O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts