Tang, Minhao published the artcileA CO2-mediated base catalysis approach for the hydration of triple bonds in ionic liquids, HPLC of Formula: 107-54-0, the main research area is carbonyl compound preparation green chem; nitrile alkyne hydration carbon dioxide ionic liquid.
Herein, a CO2-mediated base catalysis approach for the activation of triple bonds in ionic liquids (ILs) with anions that can chem. capture CO2 (e.g., azolate, phenolate, and acetate), which can achieve hydration of triple bonds to carbonyl chems. is reported. It is discovered that the anion-complexed CO2 could abstract one proton from proton resources (e.g., IL cation) and transfer it to the CN or CC bonds via a six-membered ring transition state, thus realizing their hydration. In particular, tetrabutylphosphonium 2-hydroxypyridine shows high efficiency for hydration of nitriles and CC bond-containing compounds under a CO2 atmosphere, affording a series of carbonyl compounds in excellent yields. This catalytic protocol is simple, green, and highly efficient and opens a new way to access carbonyl compounds via triple bond hydration under mild and metal-free conditions.
Green Chemistry published new progress about Alcohols, propargyl Role: RCT (Reactant), RACT (Reactant or Reagent). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, HPLC of Formula: 107-54-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts