Liu, Hui-Min published the artcileDehydrogenation of Alcohols to Carboxylic Acid Catalyzed by in Situ-Generated Facial Ruthenium-CPP Complex, Related Products of alcohols-buliding-blocks, the main research area is carboxylic acid preparation dehydrogenation alcs facial Ruthenium phosphine catalyst.
A selective catalytic system for the dehydrogenation of primary alcs. to carboxylic acids using a facial ruthenium complex generated in situ from the [Ru(COD)Cl2]n and a hybrid N-heterocyclic carbene (NHC)-phosphine-phosphine ligand (CPP) has been first reported. The facial coordination model was unveiled by NMR anal. of the reaction mixture Such a fac-ruthenium catalyst system exhibited high catalytic activity and stability, and a high turnover number of 20 000 could be achieved with catalyst loading as low as 0.002 mol %. The exceedingly high catalyst stability was tentatively attributed to both the anchoring role of NHC and the hemi-lability of phosphines. The catalytic system also features a wide substrate scope. In particular, the facial coordination of CPP ligands was found to be beneficial for sterically hindered alcs., and ortho-substituted benzylic alcs. and bulky adamantanyl methanol as well as cholesterol were all found to be viable dehydrogenation substrates.
Journal of Organic Chemistry published new progress about Benzoic acids Role: SPN (Synthetic Preparation), PREP (Preparation). 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Related Products of alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts