Bhattacharyya, Dipanjan published the artcileSelective Catalytic Synthesis of α-Alkylated Ketones and β-Disubstituted Ketones via Acceptorless Dehydrogenative Cross-Coupling of Alcohols, Name: 3-Pentanol, the main research area is primary alkanol aryl secondary alc ruthenium catalyst selective alkylation; arylethanol secondary alc ruthenium catalyst selective dehydrogenative cross coupling; aryl alkanone preparation green chem.
A phosphine-free pincer ruthenium(III) catalyzed β-alkylation of secondary alcs. with primary alcs. to α-alkylated ketones and two different secondary alcs. to β-branched ketones were reported. Notably, this transformation was environmentally benign and atom efficient with H2O and H2 gas as the only byproducts. The protocol was extended to gram-scale reaction and for functionalization of complex vitamin E and cholesterol derivatives
Organic Letters published new progress about Alkyl aryl ketones Role: SPN (Synthetic Preparation), PREP (Preparation). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Name: 3-Pentanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts