Bai, Xishan published the artcileHydrogen-Borrowing Amination of Secondary Alcohols Promoted by a (Cyclopentadienone)iron Complex, Formula: C5H12O, the main research area is hydrogen borrowing amination secondary alc cyclopentadienone iron complex catalyst.
Thanks to a highly active catalyst, the scope of the (cyclopentadienone)iron complex-promoted ‘hydrogen-borrowing’ (HB) amination has been expanded to secondary alcs., which had previously been reported to react only in the presence of large amounts of co-catalysts [e.g., p-anisidine + 1-phenylethanol â?N-(4-methoxyphenyl)-1-phenylethylamine (89% conversion) in presence of mol. sieves with amine:alc. stoichiometry of 4:1 at 150° in toluene]. A range of cyclic and acyclic secondary alcs. were reacted with aromatic and aliphatic amines giving fair to excellent yields of the substitution products. The catalyst was also able to promote the cyclization of diols bearing a secondary alc. group with primary amines to generate saturated N-heterocycles.
Synthesis published new progress about Aliphatic amines Role: RCT (Reactant), RACT (Reactant or Reagent). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Formula: C5H12O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts