Inokuchi, Tsutomu’s team published research in Journal of Organic Chemistry in 1990-03-02 | CAS: 42822-86-6

Journal of Organic Chemistry published new progress about Carboxylic acids, epoxy, esters Role: RCT (Reactant), RACT (Reactant or Reagent). 42822-86-6 belongs to class alcohols-buliding-blocks, name is 2-(2-Hydroxypropan-2-yl)-5-methylcyclohexanol, and the molecular formula is C10H20O2, Product Details of C10H20O2.

Inokuchi, Tsutomu published the artcileElectroreductive ring-opening of α,β-epoxy carbonyl compounds and their homologs through recyclable use of diphenyl diselenide or diphenyl ditelluride as a mediator, Product Details of C10H20O2, the main research area is electrochem ring cleavage epoxy carbonyl compound; aldol; hydroxy ketone; nitrile hydroxy; ester hydroxy; regiochem reduction cleavage epoxy carbonyl.

A novel access to β-hydroxy carbonyl compounds from the corresponding α,β-epoxy carbonyl compounds is attained by the recyclable use of Ph2Se2 or Ph2Te2 as an electroreduction mediator in a MeOH-NaClO4-Pt system. α,β-Epoxy ketones are converted to the corresponding aldols in the presence of malonic esters. Similarly, α,β-epoxy esters and nitriles are reduced to the corresponding β-hydroxy compounds in the presence of AcOH.

Journal of Organic Chemistry published new progress about Carboxylic acids, epoxy, esters Role: RCT (Reactant), RACT (Reactant or Reagent). 42822-86-6 belongs to class alcohols-buliding-blocks, name is 2-(2-Hydroxypropan-2-yl)-5-methylcyclohexanol, and the molecular formula is C10H20O2, Product Details of C10H20O2.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts