Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols was written by Zhu, Yuchao;Huang, Kaimeng;Pan, Jun;Qiu, Xu;Luo, Xiao;Qin, Qixue;Wei, Jialiang;Wen, Xiaojin;Zhang, Lizhi;Jiao, Ning. And the article was included in Nature Communications in 2018.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:
Herein, a silver-catalyzed δ-selective Csp3-H bond functionalization of abundant and inexpensive aliphatic alcs is reported. Valuable oximonitrile substituted alcs. I (R = Et, n-Bu, Bn, etc.) are easily obtained by using well-designed sulfonyl reagents under simple and mild conditions. This protocol realizes the challenging δ-selective C-C bond formation of simple alkanols. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.HPLC of Formula: 106-21-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts