Chemoselective Aliphatic C-H Bond Oxidation Enabled by Polarity Reversal was written by Dantignana, Valeria;Milan, Michela;Cusso, Olaf;Company, Anna;Bietti, Massimo;Costas, Miquel. And the article was included in ACS Central Science in 2017.SDS of cas: 106-21-8 The following contents are mentioned in the article:
Using nonracemic manganese complexes, alkanes, alcs., amides, and amines underwent chemoselective and regioselective hydroxylation with H2O2 at unactivated C-H bonds when performed in fluorinated alc. solvents (particularly hexafluoroisopropanol and 2,2,2-trifluoroethanol) to yield monohydroxylated products with improved chemoselectivities relative to reactions performed in MeCN. The initial hydroxylated product is oxidized much less readily in fluoroalc. solvents than in MeCN. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8SDS of cas: 106-21-8).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.SDS of cas: 106-21-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts