Wendeln, Christian published the artcileCarbohydrate Microarrays by Microcontact Printing, Synthetic Route of 87905-98-4, the main research area is carbohydrate microarray microcontact printing.
This Article describes the preparation of carbohydrate microarrays by the immobilization of carbohydrates via microcontact printing (μCP) on glass and silicon substrates. To this end, diene-modified carbohydrates (galactose, glucose, mannose, lactose, and maltose) were printed on maleimide-terminated self-assembled monolayers (SAMs). A Diels-Alder reaction occurred exclusively in the contact area between stamp and substrate and resulted in a carbohydrate pattern on the substrate. It was found that cyclopentadiene-functionalized carbohydrates could be printed within minutes at room temperature, whereas furan-functionalized carbohydrates required long printing times and high temperatures By successive printing, microstructured arrays of up to three different carbohydrates could be produced. Immobilization and patterning of the carbohydrates on the surfaces was investigated with contact angle measurements, XPS, time-of-flight secondary ion mass spectrometry (TOF-SIMS), and fluorescence microscopy. Furthermore, the lectins Con A (ConA) and peanut agglutinin (PNA) bind to the microarrays, and the printed carbohydrates retain their characteristic selectivity toward these proteins.
Langmuir published new progress about Carbohydrates Role: ARG (Analytical Reagent Use), BUU (Biological Use, Unclassified), PEP (Physical, Engineering or Chemical Process), RCT (Reactant), SPN (Synthetic Preparation), TEM (Technical or Engineered Material Use), ANST (Analytical Study), USES (Uses), BIOL (Biological Study), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation) (diene-modified). 87905-98-4 belongs to class alcohols-buliding-blocks, name is Benzyl (5-hydroxypentyl)carbamate, and the molecular formula is C13H19NO3, Synthetic Route of 87905-98-4.
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