Ponomarev, A. V. published the artcileAcceleration of radical exchange and combination in 1-propanol under irradiation and boiling, Application In Synthesis of 584-02-1, the main research area is propanol radical bond cleavage radiolysis reaction mechanism.
The yield of radiolytic degradation of 1-propanol is 13.3 ± 0.9 mols./100 eV in a boiling state and 10.1 ± 0.9 mols./100 eV in ambient conditions when irradiated with 8 MeV accelerated electrons. Boiling increases the yields of diols by 1.7 times and of heavy monohydric alcs. arising via the radical combination by 1.3 times. At the same time, due to boiling, the total yield of methanol and ethanol decreases 2.1 times, and the yield of aldehydes and hydrocarbons – 1.3 times. Boiling accelerates the dissociation of some radicals and radical-cations, facilitates the radical exchange and favors a combination of hydroxypropyl radicals. However, both in liquid and boiling alc., the total yield of splitting of C-H bonds remains approx. twice as high as C-C bonds.
Radiation Physics and Chemistry published new progress about C-C bond cleavage. 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Application In Synthesis of 584-02-1.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts