Pardatscher, Lorenz published the artcileHighly Efficient Abnormal NHC Ruthenium Catalyst for Oppenauer-Type Oxidation and Transfer Hydrogenation Reactions, SDS of cas: 584-02-1, the main research area is cationic ruthenium phosphinoethylimidazolylidene carbene complex preparation catalyst transfer hydrogenation; crystal structure cationic ruthenium phosphinoethylimidazolylidene carbene complex; mol structure cationic ruthenium phosphinoethylimidazolylidene carbene complex; oxidation catalyst cationic ruthenium phosphinoethylimidazolylidene carbene complex.
The Ru complex [Ru(OAc)(a-PC)2]Br (3) containing two abnormal NHC ligands was obtained by reaction of Ru(OAc)2(PPh3)2 (1) with 1-(2-diphenylphosphinoethyl)-3-mesitylimidazolium bromide in the presence of NaOAc. Complex 3 catalyzes the Oppenauer-type oxidation of a number of alcs. at unrivalled reaction rates reaching TOFs up to 550,000 h-1, at low catalyst loadings (S/C >10,000) and using acetone in stoichiometric amounts Complex 3 is also highly active in the reverse transfer hydrogenation of several ketones with iso-PrOH, displaying TOFs up to 600,000 h-1.
ACS Catalysis published new progress about Crystal structure. 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, SDS of cas: 584-02-1.
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