Lu, Fu-Dong published the artcilePhotoinduced C-O bond cleavage for copper-catalyzed allenyl radical cyanation, Related Products of alcohols-buliding-blocks, the main research area is allenyl nitrile chemoselective preparation; alkyl alkynyl benzoate photoinduced CO bond cleavage copper catalyst.
In this work, allenyl radicals were generated by the photoinduced cleavage of carbon-oxygen bonds, and participated in the copper catalytic cycle, affording structurally diverse and highly significant allenyl nitriles R(CN)C=C=CR1R2 [R = H, n-Bu; R1 = t-Bu, Ph, 3-thienyl, etc.; R2 = H, Me, n-Pr, etc.]. Both 1,3-disubstituted allenyl nitriles and trisubstituted allenyl nitriles could be assembled with moderate to good yields (24 examples, 65-95% yields) and high chemoselectivity. To prove the utility of this new methodol., an allene nitrile was converted into other valuable synthetic blocks including an allyl nitrile, alkyl nitrile and α-cyano cyclic ketone.
Organic Chemistry Frontiers published new progress about Allenes Role: SPN (Synthetic Preparation), PREP (Preparation). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Related Products of alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts