Gao, Han published the artcileTransition Metal-Free Radical α-Oxy C-H Cyclobutylation via Photoinduced Hydrogen Atom Transfer, Recommanded Product: 3-Pentanol, the main research area is oxyalkane arylsulfonyl bicyclobutane regioselective quinuclidine photocatalyst ring opening; arylsulfonyl cyclobutane preparation.
A transition-metal-free photoinduced radical-mediated α-oxy C-H cyclobutylation reaction of bicyclo[1.1.0]butane (BCB) compounds was described. In this protocol, α-oxy C(sp3)-H motifs including ethers and alcs. were activated via photocatalytic conditions, releasing the ring strain of BCBs and generating 1,3-disubstituted cyclobutanes in 40-80% yields. Control experiments and Stern-Volmer quenching experiments indicated that the reaction proceeded through the generation of α-oxy carbon-centered radical intermediates by photoinduced hydrogen atom transfer (HAT) process.
Advanced Synthesis & Catalysis published new progress about Aromatic compounds, sulfones Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, Recommanded Product: 3-Pentanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts