Tota, Arianna’s team published research in Advanced Synthesis & Catalysis in 363 | CAS: 622-40-2

Advanced Synthesis & Catalysis published new progress about 622-40-2. 622-40-2 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Alcohol, name is 2-Morpholinoethanol, and the molecular formula is C5H6BNO2, Related Products of alcohols-buliding-blocks.

Tota, Arianna published the artcileN-N Bond Formation Using an Iodonitrene as an Umpolung of Ammonia: Straightforward and Chemoselective Synthesis of Hydrazinium Salts, Related Products of alcohols-buliding-blocks, the publication is Advanced Synthesis & Catalysis (2021), 363(1), 194-199, database is CAplus.

The formation of hydrazinium salts by N-N bond formation has typically involved the use of hazardous and difficult to handle reagents. Here, mild and operationally simple conditions for the synthesis of hydrazinium salts are reported. Electrophilic nitrogen transfer to the nitrogen atom of tertiary amines is achieved using iodosylbenzene as oxidant and ammonium carbamate as the N-source. The resulting process is highly chemoselective and tolerant to other functional groups. A wide scope is reported, including examples with bioactive mols. Insights on the structure of hydrazinium salts were provided by X-ray anal.

Advanced Synthesis & Catalysis published new progress about 622-40-2. 622-40-2 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Alcohol, name is 2-Morpholinoethanol, and the molecular formula is C5H6BNO2, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts