Noh, Chanho published the artcileOptimization of iron and cobalt based organometallic redox couples for long-term stable operation of aqueous organometallic redox flow batteries, Product Details of C9H21NO3, the publication is Journal of Power Sources (2021), 229799, database is CAplus.
The optimal electrolyte condition for iron (Fe) and cobalt (Co) coordinated with Triisopropanolamine (TiPA) and 3-[Bis(2-hydroxyethyl)amino]-2-hydroxypropanesulfonic acid (DIPSO) is suggested for aqueous organometallic redox flow batteries (AMORFBs), while best combination for improving its long-term stability is determined Co(TiPA) is optimal catholyte due to excellent redox reactivity and stability, while such benefits are proved by the comparison of formation constant which is proportional to the strength of coordination bonds within metal complex. That of Co(TiPA) is 10.8 times higher than that of Co(DIPSO) that is a competitor for catholyte. Regarding anolyte, Fe(DIPSO) formed by 1:1.5 mol ratio of Fe ion to DIPSO ligand is more stable than Fe(TiPA) that is a competitor for anolyte. The stability is exptl. verified by linear sweep voltamogram. According to the measurements, In Fe(DIPSO), potential required for the solidification of Fe ions, which causes the performance degradation of AMORFB, is placed more neg. than that required in Fe(TiPA). This indicates the when Fe(DIPSO) is used, the stable cut-off voltage range for AMORFB tests is extended with its performance improvement. Furthermore, since the solidified Fe further acts as catalyst for undesirable hydrogen evolution reaction, retarding the solidification of Fe ions enhances the performance and stability of AMORFB. In in-situ AMORFB cell tests performed to validify the electrochem. evaluations of metal complexes, the stability of AMORFB using Co(TiPA) and Fe(DIPSO) is best. Regarding its performance, charge capacity is high as 15.5 Ah L-1, while its capacity loss rate is low as 0.018 Ah L-1cyc-1 for 100 cycles.
Journal of Power Sources published new progress about 122-20-3. 122-20-3 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment, name is Triisopropanolamine, and the molecular formula is C9H21NO3, Product Details of C9H21NO3.
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