Eswaramoorthy, Senthil Kumar published the artcileAtomically Precise Palladium Nanoclusters with 21 and 38 Pd Atoms Protected by Phenylethanethiol, Application In Synthesis of 4410-99-5, the publication is Journal of Physical Chemistry C (2022), 126(1), 444-450, database is CAplus.
Monolayer thiolate-protected nanoclusters (MPCs) are extensively studied due to their distinctive properties. The at. precision in MPCs, especially in gold MPCs, is determined through mass spectrometry, which leads to the accurate identification of metal-ligand composition The total structure determination of gold and silver MPCs using ScXRD revolutionized the field by providing insights into the structural arrangement at an at. level. The synthesis of atomically precise MPCs using other metals like palladium (Pd) to study and compare properties is tedious and complex. In one end, larger size monodisperse Pd nanoparticles (NPs) were synthesized and studied for various catalytic properties. Meanwhile, on the other end, a small-mol. tiara-like Pd-thiolate complex was reported. However, at. precise Pd MPCs in the middle and its detailed studies are not yet explored. Here, we report the synthesis and identification of atomically precise phenylethanethiol-protected Pd21(SCH2CH2Ph)18 and Pd38(SCH2CH2Ph)21S2 Pd nanoclusters. The size distribution is confirmed using matrix-assisted laser desorption ionization mass spectra (MALDI-MS), and electrospray ionization mass spectrometry (ESI-MS) confirms the composition through the isotopically resolved peak. The XPS spectra elucidate the cluster formation in smaller size.
Journal of Physical Chemistry C published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C8H10S, Application In Synthesis of 4410-99-5.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts